Elemental

This is for the alchemical apprentices of the House of the Wyvern. Herein may be found accounts and recipes of the molecular arts.


Tuesday, January 30, 2007

Mock Examination Material

For those who would like to have some experience in past years' papers from the A-Level system, this page has been kindly provided by the people who administer that.

Look here. Answer schemes are provided as well!

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In Summary

I'd just like to point out that at this present moment, all classes should be aware of the following points:

1. There are four important areas to examine in organic chemistry, compounds, reactions and mechanisms. These are: electronic factors, steric factors, thermodynamic factors and kinetic factors.

2. There are a few major mechanisms with variations. One way to look at the range of mechanisms is: a) look at the attacking species - nucleophile, electrophile, free radical etc; b) look at the outcome - substitution, addition, elimination etc; c) consider the molecularity - likely to be unimolecular or bimolecular. Another way is to put these together and get mechanisms such as free radical substitution, electrophilic addition, electrophilic substitution, Sn1, Sn2, E1, E2 and so on. You should be able to explain all the reactions to some extent at this point, using structural diagrams and arrows.

3. This doesn't take away your responsibility to be able to classify compounds, name the easier ones (8 or fewer carbon, I'd say, but 6 or fewer is OK), and draw them. You should know these kinds at least: alkanes, alkenes, haloalkanes, alcohols, aldehydes, ketones, carboxylic acids, amides, acyl halides, acid anhydrides, esters, and simple (one ring) aromatic compounds. It's nice if you know alkynes and other stuff, but we'll cover some of that later on.
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Thursday, January 11, 2007

Reaction Mechanisms

'Reaction mechanisms in organic chemistry' is pretty straightforward topic if you remember a few key ideas.

1. Factors to consider: electronic, steric, thermodynamic, kinetic

2. Active species involved: free radical, nucleophile, electrophile

3. Overall consequence: substitution, addition, elimination


Here are two very helpful links:

1. List of Wikipedia entries for organic chemistry reaction mechanisms

2. ChemGuide index for organic chemistry reaction mechanisms

Personally, I prefer Wikipedia when I am looking for many related concepts and how they work together. I prefer Chemguide when I'm looking for clear specific ideas related to academic course requirements. Between the two, students should be able to figure out the basic principles of organic reactions.
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Wednesday, January 03, 2007

Organic Chemistry 102

For those who still don't know what's being covered in the IBDP syllabus, please look at:

Organic Chemistry - Topic 20 (HL)
Further Organic Chemistry - Option H

Also check out related links on the rest of the page.
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Tuesday, January 02, 2007

Organic Chemistry 101

Hello, ladies and gentlemen.

Welcome to a new year of chemical exploits (not explosions!)

Please go to this site to do some basic reading in organic chemistry before you will be ready. Explore as much as you can in the given sequence by the second week of term.

More advanced students might want to take note of this resource as well.

Thank you!
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